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Document Details
Document Type
:
Article In Journal
Document Title
:
Surface enhanced Raman spectroscopy as a new spectral technique for quantitative detection of metal ions
Surface enhanced Raman spectroscopy as a new spectral technique for quantitative detection of metal ions
Document Language
:
English
Abstract
:
Four newly synthesized poly (propylene amine) dendrimers from first and second generation modified with 1,8-naphthalimide units in the dendrimer periphery have been investigated as ligands for the detection of heavy metal ions (Al3+, Sb2+, As2+, Cd2+ and Pb2+) by surface-enhanced Raman spectroscopy. Calibration curves were established for all metal ions between the concentration ranges of 1 x 10(-6) to 5 x 10(-4) M. It has been shown that these dendrimers can be coordinated, especially with different metal ions. Using dendrimer molecules and silver colloids at the same time allowed us to obtain an SERS signal from the abovementioned metal ions at very low concentrations. Principle component analysis (PCA) analysis was also applied to the collected SERS data. Four differentPCA models were developed to accomplish the discrimination of five metal ions, which interacted with each of the four dendrimer molecules, separately. A detailed investigation was performed in the present study to provide the basis of a new approach for heavy metal detection.
ISSN
:
1386-1425
Journal Name
:
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Volume
:
116
Issue Number
:
116
Publishing Year
:
1434 AH
2013 AD
Article Type
:
Article
Added Date
:
Monday, July 17, 2017
Researchers
Researcher Name (Arabic)
Researcher Name (English)
Researcher Type
Dr Grade
Email
T Temiz
Temiz, T
Researcher
H Boyaci
Boyaci, H
Researcher
i Grabchev
Grabchev, i
Researcher
U Tamer
Tamer, U
Researcher
Files
File Name
Type
Description
42037.pdf
pdf
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